Author: Michael Engel

In a joint collaboration combining experiment (synthesis and self-assembly), analysis (electron microscopy including tomography), and simulation (molecular dynamics and free energy calculations), a team from FAU involving Junwei Wang and Chrameh Mbah reported magic number colloidal clusters:

“Clusters in systems as diverse as metal atoms, virus proteins, noble gases, and nucleons have properties that depend sensitively on the number of constituent particles. Certain numbers are termed ‘magic’ because they grant the system with closed shells and exceptional stability. To this point, magic number clusters have been exclusively found with attractive interactions as present between atoms. Here we show that magic number clusters exist in a confined soft matter system with negligible interactions. Colloidal particles in an emulsion droplet spontaneously organize into a series of clusters with precisely defined shell structures. Crucially, free energy calculations demonstrate that colloidal clusters with magic numbers possess higher thermodynamic stability than those off magic numbers. A complex kinetic pathway is responsible for the efficiency of this system in finding its minimum free energy configuration. Targeting similar magic number states is a strategy towards unique configurations in finite self-organizing systems across the scales.”

Read about it here:

Magic Number Colloidal Clusters as Minimum Free Energy Structures
J. Wang, C.F. Mbah, T. Przybilla, B.A. Zubiri, E. Spiecker, M. Engel, N. Vogel
Nature Communications 9, 5259 (2018)

In a recent ACS Nano publication, Alberto Leonardi proposes an etching synthesis method for controlling the shape of core-shell nanocrystals:

“The application of nanocrystals as heterogeneous catalysts and plasmonic nanoparticles requires fine control of their shape and chemical composition. A promising idea to achieve synergistic effects is to combine two distinct chemical and/or physical functionalities in bimetallic core@shell nanocrystals. Although techniques for the synthesis of single-component nanocrystals with spherical or anisotropic shape are well-established, new methods are sought to tailor multicomponent nanocrystals. Here, we probe etching in a controlled redox environment as a synthesis technique for multicomponent nanocrystals. Our Monte Carlo computer simulations demonstrate the appearance of characteristic non-equilibrium intermediate microstructures that are further thermodynamically tested and analyzed with molecular dynamics. Convex platelet, concave polyhedron, pod, cage, and strutted-cage shapes are obtained at room temperature with fully coherent structure exposing crystallographic facets and chemical elements along distinct particle crystallographic directions. We observe that structural and dynamic properties are markedly modified compared to the untreated compact nanocrystal.”

Read about it here:

Particle Shape Control via Etching of Core-Shell Nanocrystals
A. Leonardi, M. Engel
ACS Nano 12, 9186-9195 (2018)